An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs   总被引：7，自引：0，他引：7  

Cécile Grosbois  Philippe Négrel  Daniel Grimaud  Christian Fouillac 《Aquatic Geochemistry》2001,7(2):81-105

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.  相似文献   

Evaluation of Pb-Pb and U-Pb Laser Ablation ICP-MSZircon Dating using Matrix-Matched Calibration Sampleswith a Frequency Quadrupled (266 nm)Nd-YAG Laser     

Olivier Bruguier  Philippe Télouk  Alain Cocherie  Anne-Marie Fouillac  Francis Albarède 《Geostandards and Geoanalytical Research》2001,25(2-3):361-373

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Fine sediment transport and accumulations at the mouth of the Seine estuary (France)     

Pierre Le Hir  Andre Ficht  Ricardo Silva Jacinto  Patrick Lesueur  Jean-Paul Dupont  Robert Lafite  Isabelle Brenon  Benedicte Thouvenin  Philippe Cugier 《Estuaries and Coasts》2001,24(6):950-963

A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year.  相似文献   

一个改进的湍流垂直扩散过程参数化方案     

陈德辉  秦成  Philippe Bougeault 《气象学报》1996,54(3):333-347

研究了数值天气预报模式中次阿格湍流垂直扩散过程的参数化问题。以Ｂｏｕｇｅａｕｌｔ和Ｌａｃａｒｒｅｒｅ（１９８９）的参数化方案为基础，改进了处理湍流混合长的方法，使湍流混合长和热力混合长分别依赖于基本气流的静力稳定度和风场切变。新方案的基本思路是把ＶｏｎＫａｒｍａｎ（１９３０）提出的动力（风场切变）湍流扰动假设与ＢＬ－８９方案提出的热力（静力稳定度）湍流扰动假设结合在一起，强调了大气的热力结构、动力结构和湍流动能对湍流混合过程的共同影响。新方案和ＢＬ－８９方案的二维对比数值试验结果表明，在大气处于静力较稳定而风场切变明显条件下的湍流扰动表现能力方面，新方案比原方案有明显的改进。  相似文献   

himu-em: The French Polynesian connection     

Catherine Chauvel  Albrecht W. Hofmann  Philippe Vidal 《Earth and Planetary Science Letters》1992,110(1-4)

himu, em i andem ii are three of the main geochemical mantle components that give rise to oceanic island basalts [1]. They represent the end members that produce the extreme isotopic compositions measured on intraplate volcanics. In French Polynesia, all three mantle components are represented in volcanic rocks. The characteristichimu signature is found in Tubuai, Mangaia and Rurutu,em i is present in the source of Rarotonga and Pitcairn volcanics andem ii dominates the composition of most Society Islands. Intermediate values between the three end members are found on most islands.We suggest that the three components are not independent but are physically related in the mantle. Thehimu component is thought to be recycled oceanic crust that lost part of its Pb through hydrothermal processes prior to and during subduction.em i andem ii are believed to acquire their isotopic and trace element characteristics through entrainment of sediments that were subducted together with the oceanic crust.The trace element pattern and the isotopic composition ofhimu lavas can be quantitatively modelled using a mixture of 25% old recycledmorb crust and 75% mantle peridotite. The extreme Pb composition is modelled assuming that Pb was lost from oceanic crust when hydrothermal alteration at the ridge leached Pb from the basalt to redeposit it as sulphides on top of and throughout the crust, followed by preferential dissolution of sulphides during dehydration in the subduction zone. These processes led to a drastic increase of theU/Pb ratio of the subducted material which evolved over 2 Ga to very radiogenic Pb isotopic compositions. Pb isotopic compositions similar to those ofem i andem ii are modelled assuming that sediments with average crustal Pb isotopic compositions were subducted and recycled into the mantle together with the underlyingmorb oceanic crust. Pelagic sediments (μ 5 andκ 6) account for the Pb isotopic composition ofem i whereas terrigenous sediments (μ 10 andκ 4.5) evolve towards theem ii end member. A few percent of sediment in the recycled crust-sediment mixture will destroy the characteristic Pb isotopic signature of thehimu component. This, together with the low probability of isolating oceanic crust in the mantle for 2 Ga, explains why the extremehimu composition, as seen on Tubuai and St Helena, is sampled so rarely by oceanic volcanism.  相似文献   

Hydrothermal alterations in the Echassières granitic cupola (Massif central,france)     

Thierry Merceron  Philippe Vieillard  Anne-Marie Fouillac  Alain Meunier 《Contributions to Mineralogy and Petrology》1992,112(2-3):279-292

Detailed petrographic and mineralogic investigations of an albite-lepidolite granite at Echassières (Massif Central, France; scientific deep drill program) shows the existence of hydrothermal stages which are closely related to the magmatic and structural history. According to fluid inclusion data, K-Ar datations and ¹⁸O/¹⁶O-D/H compositions of secondary minerals, two successive hydrothermal periods have been recognized. The early one (273–268 million years) produced a series of aluminous phyllosilicates: muscovite, pyrophyllite, donbassite, tosudite, kaolinite which are observed as vein deposits (<10 mm wide) and alteration products of primary minerals in wall-rocks. The vein system was sealed by monomineralic assemblages during a cooling period (400–150°C). This early hydrothermal alteration stage was controlled by interactions of rock with low salinity (1–10 wt% NaCl equivalent) fluids expelled from the granitic body during the cooling processes. The chemical properties of these fluids were the following: low pH, very low Mg and Fe and high Li, Na and K contents. Thermodynamic calculations show that the sequence pyrophyllite, Li-bearing donbassite, tosudite is mostly temperature dependent. From the chemical composition of secondary minerals and isotopic data it can be deduced that these fluids, which have a meteoric origin, have been expelled from the granite body during its cooling period and after interaction with it at high temperature. The late hydrothermal stage corresponds to deposits of fluorite and Fe-Mg rich illite (151 million years) in subvertical fractures. Temperature conditions did not exceed 250° C and fluids came through the surrounding metamorphic rocks into the granitic body. IIlite/smectite mixed-layer minerals have been identified in subvertical fractures which were opened during Tertiary periods. In the host micaschists, successive hydrothermal alterations took place during the cooling of the Beauvoir granite. Early magmatic fluids interacted with these micaschists. Locally, the metamorphic assemblage is replaced by a metasomatic one. Secondary topaz and (F, Li)-rich mica crystals were formed over a range of 450 of 150°C. Later hydrothermal fluids reacted with the country rocks to form phengite-biotite, chlorite-illite and kaolinite over a range of 300 to 150°C. Illite/smectite mixed-layer minerals crystallized in the roof micaschists and within the Beauvoir granite during the Tertiary alteration period. Meteoric water invaded open fractures producing supergene alteration mineral assemblages.  相似文献   

La prévision du climat : de l'échelle saisonnière à l'échelle décennale     

Jean-Claude Andr  Jean-Yves Caneill  Michel Dqu  Philippe Rogel  Laurent Terray  Yves Tourre 《Comptes Rendus Geoscience》2002,334(16):1115

The atmosphere and the ocean are subject to many dynamical instabilities, which limit the time during which their behaviour can be deterministically forecasted. At longer timescales, the atmosphere can be predicted at best using statistical methods, as a response to external forcing linked to sea- and land-surface anomalies. Climate being defined as the mean of atmospheric states, it appears that it can be predicted up to a few months in advance, which is the characteristic time of the so-called slow components of the climate system. Forecasting can sometimes be extended to longer time ranges, especially when the coupled ocean–atmosphere system exhibits internal variability modes, with characteristic times of a few years. Seasonal climate forecasting is most often based upon Monte-Carlo simulations, where the various realisations correspond to slightly different initial conditions. The present sate-of-the-art in Europe (ECMWF) and/or in the USA (IRI) allows to forecast such major phenomena, as El Niño, up to six months in advance. Finally, some parameters may exhibit predictability at still longer time-ranges (inter-annual to decadal), but only for certain regions. The example of electricity production is used to underline the potentially large economical benefit of seasonal climate forecasting. To cite this article: J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.

Résumé

L'atmosphère et l'océan sont le siège d'instabilités dynamiques, qui limitent la durée pendant laquelle il est possible d'en prévoir l'évolution de façon déterministe. Au-delà, l'atmosphère n'est plus prévisible, au mieux, que de façon statistique, en fonction du forçage externe qu'exerce(nt) sur elle l'océan et/ou la surface des continents. Le climat (au sens d'une moyenne des états atmosphériques) se révèle ainsi prévisible jusqu'à des échéances temporelles de quelques mois, échelle de temps caractéristique des composantes dites « lentes » du système climatique. La prévision peut s'étendre à des échéances parfois plus longues, dans le cas où le système couplé océan–atmosphère posséderait des modes de variabilité temporelle de périodes caractéristiques de quelques années. La prévision climatique saisonnière est très souvent construite à partir de simulations de type Monte-Carlo, avec des ensembles de réalisations utilisant des conditions initiales légèrement différentes. Dans l'état actuel de ces prévisions, qu'elles soient réalisées en Europe (CEPMMT) ou aux États-Unis (IRI), il est possible de prévoir environ six mois à l'avance un certain nombre de phénomènes climatiques, en particulier ceux liés aux épisodes dits « El Niño », pour lesquels l'amplitude des variations est suffisamment importante. Il existe, par ailleurs, une prévisibilité à encore plus longue échéance (inter-annuelle à décennale), mais seulement pour certains paramètres et certaines régions. L'exemple de la production d'électricité montre l'importance économique potentielle très grande de la prévision climatique saisonnière. Pour citer cet article : J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.  相似文献   

Steady- and transient-state inversion in hydrogeology by successive flux estimation     

Philippe Pasquier  Denis Marcotte 《Advances in water resources》2006,29(12):1934-1952

A calibration method to solve the groundwater inverse problem under steady- and transient-state conditions is presented. The method compares kriged and numerical head field gradients to modify hydraulic conductivity without the use of non-linear optimization techniques. The process is repeated iteratively until a close match with piezometric data is reached. The approach includes a damping factor to avoid divergence and oscillation of the solution in areas of low hydraulic gradient and a weighting factor to account for temporal head variation in transient simulations. The efficiency of the method in terms of computing time and calibration results is demonstrated with a synthetic field. It is shown that the proposed method provides parameter fields that reproduce both hydraulic conductivity and piezometric data in few forward model solutions. Stochastic numerical experiments are conducted to evaluate the sensitivity of the method to the damping function and to the head field estimation errors.  相似文献   

A preliminary investigation of strong-motion data from the French Antilles     

John Douglas  Didier Bertil  Agathe Roullé  Pascal Dominique  Philippe Jousset 《Journal of Seismology》2006,10(3):271-299

Strong-motion networks have been operating in the Caribbean region since the 1970s, however, until the mid-1990s only a few analogue stations were operational and the quantity of data recorded was very low. Since the mid-1990s, digital accelerometric networks have been established on islands within the region. At present there are thought to be about 160 stations operating in this region with a handful on Cuba, 65 on the French Antilles (mainly Guadeloupe and Martinique), eight on Jamaica, 78 on Puerto Rico (plus others on adjacent islands) and four on Trinidad.After briefly summarising the available data from the Caribbean islands, this article is mainly concerned with analysing the data that has been recorded by the networks operating on the French Antilles in terms of their distribution with respect to magnitude, source-to-site distance, focal depth and event type; site effects at certain stations; and also with respect to their predictability by ground motion estimation equations developed using data from different regions of the world. More than 300 good quality triaxial acceleration time-histories have been recorded on Guadeloupe and Martinique at a large number of stations from earthquakes with magnitudes larger than 4.8, however, most of the records are from considerable source-to-site distances. From the data available it is found that many of the commonly-used ground motion estimation equations for shallow crustal earthquakes poorly estimate the observed ground motions on the two islands; ground motions on Guadeloupe and Martinique have smaller amplitudes and are more variable than expected. This difference could be due to regional dependence of ground motions because of, for example, differing tectonics or crustal structures or because the ground motions so far recorded are, in general, from smaller earthquakes and greater distances than the range of applicability of the investigated equations.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献